铌钛微合金钢异型坯高温塑性研究

在GLLEEBLE3800热模拟试验机上进行了铌钛复合微合金化钢异型坯的高温拉伸试验,并对断口形貌进行了分析,确定了钢材的脆性温度区,第I脆性区的温度范围为1 300℃至熔点,高温塑性区的温度范围为950～1 300℃,第Ⅲ脆性区的温度范围为700～900℃,高温塑性区为微孔聚集韧性断裂,呈现典型的韧窝结构,在第Ⅲ脆性区为准解理断裂,呈现典型的河流花样结构。     

Cross‐Linked Fluorinated Poly(Aryl Ether) (C‐FPAE) Films: Preparation Strategy,Performance Study,and Low Dielectric Applications

The production of low dielectric materials that can be used in high temperature environments is the primary aim of this work. A cross‐linked structure is introduced into fluorinated poly(aryl ether) (named as FPAE) with high molecular weight (M_w, 140 000 g mol^?1) and linear molecular structure using nucleophilic substitution reaction at the ortho‐position of decafluorobiphenyl monomer units in the FPAE molecular chain. The curing temperature and curing time are optimized and the final conditions for the cross‐linking reaction in this study are determined to be 300 °C for 1 h. Moreover, the dielectric constant and dielectric loss of the C‐FPAE film respectively are 2.67 and 0.006 at 1000 Hz when 1 wt% of crosslinking agent is added, and the cross‐linked fluorinated poly(aryl ether) film shows excellent thermal stability (T_d(5%), 495 °C), dimensional stability, hydrophobic properties, and high storage modulus in high temperature environments. Such novel low dielectric material with excellent performances has important application value in the aerospace and the integrated electronics field.     

Modeling the influence of changes in aliphatic structure on char surface area during coal pyrolysis

The influence of changes in aliphatic structure on char surface area during coal pyrolysis was modeled, and the effect was introduced to a previous char surface area model for lignite pyrolysis established based on the chemical percolation devolatilization (CPD) model. The modified model can predict not only the N₂ and CO₂ char surface area during rapid pyrolysis of three lignites but also the CO₂ char surface area of two high-volatile bituminous coals; the agreement of the modified model with experiments is improved at high temperatures. The decrease in aliphatic chain length can reduce adsorption positions around aromatic core, and decrease char surface area. When mass release is more than 55% at about 1,100 K, the predicted N₂ char surface area starts to decrease with further generation of volatiles, and the increase of predicted CO₂ char surface area with increasing generation of volatiles also become slow at the end of mass release.     

Synthesis of highly transparent and thermally stable copolyimide with fluorine-containing dianhydride and alicyclic dianhydride

The development of optical films is highly desirable for applications in flexible displayers. In this work, a copolyimide (co-PI) film with high thermal stability and high transparency was prepared by the copolymerization of 2,2′-bis(trifluoromethyl)-4,4′-diaminodiphenyl ether, cyclobutanetetracarboxylic dianhydride, and 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA). The effects of aliphatic dianhydride and fluorine dianhydride monomers on the optical, thermal, and mechanical properties of the co-PIs were discussed in detail based on the experimental results and theoretical simulations. We found that the preparation of polyimide (PI) based on the combination of two dianhydrides could obtain the PI film with excellent comprehensive performance due to nonconjugated structure and strong electron-withdrawing effect. Through the structure and composition optimization, a PI film of PI-6FDA-70 with T_g of 300 °C, T_d10% more than 500 °C, the average transparency of 90% and the elongation at the breakage more than 8% was prepared. Such molecular design provides a practical approach to develop high-performance colorless PI films. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48603.     

A New Superconductor of BeB2C Under Atmospheric Pressure

Using structure prediction software based on particle swarm optimization algorithm, we have discovered a new atmospheric superconductor BeB2C, and the electron–phonon Wannier (EPW) software was used to calculate the superconducting critical temperature, the obtained Tc?=?30.3 K, when the effective Coulomb shielding constant and the Ep-ph constant are set to 0.16 and 0.8036 respectively. At the same time, first-principles calculation method was used to study the energy bands and density of states of the material.

     

Core–shell porphyrin·multi-walled carbon nanotube hybrids linked by multiple hydrogen bonds: nanostructure and electronic communication

In this paper, multiple hydrogen bonding interaction of ureidopyrimidinone (UPM) was employed as the linking bridge for the formation of a novel porphyrin·multi-walled carbon nanotube (MWNT) hybrid, which was then used to fabricate a layer-by-layer (LbL) film composed of porphyrin-UPM·MWNT-UPM. Both in the assembled hybrid and the LbL film, porphyrin was closely attached to the surface of the MWNT under the strong multiple hydrogen bonding interaction, forming the core–shell structure. In addition, strong electronic communication was observed between porphyrin and MWNT. The hydrogen bonding association behavior between porphyrin-UPM and MWNT-UPM was attentively analyzed by UV–Vis spectra, fluorescent spectra and transmission electron microscope experiments. It was found that the hydrogen bonding interactions were crucial for the formation of the supramolecular hybrid and the LbL film as well as the occurrence of interfacial electronic communication. This result indicated that the introduction of strong noncovalent bonding interaction between donor and acceptor is an appropriate way to control the material structure and facilitate the interfacial electronic communication in the hybrids which lay the groundwork for their application in electrochemical sensors or photovoltaic devices.     

对不连续帕累托前沿的一种改进的MOEA/D

提出了一种改进的基于分解的多目标进化算法,用于解决不连续帕累托前沿的多目标优化问题中出现帕累托近似前沿分布不均匀与不完整的问题.主要的思想是通过基于密度的聚类算法将尽量逼近帕累托前沿的种群划分为若干个子种群,将不连续帕累托前沿问题转化为多个连续子问题,然后协同演化所有子种群,最后获得更为均匀与完整的帕累托解集.实验表明对于处理不连续帕累托问题的优越性.